Constrained equilibrium as a tool for characterization of deformable porous media.

نویسندگان

  • E V Vakarin
  • Yurko Duda
  • J P Badiali
چکیده

A new method for characterizing the deformable porous materials with noncritical adsorption probes is proposed. The mechanism is based on driving the adsorbate through a sequence of constrained equilibrium states with the insertion isotherms forming a pseudocritical point or a van der Waals-type loop. In the framework of a perturbation theory and Monte Carlo simulations we have found a link between the loop parameters and the host morphology. This allows one to characterize porous matrices through analyzing a shift of the pseudocritical point and a shape of the pseudospinodals.

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عنوان ژورنال:
  • The journal of physical chemistry. B

دوره 111 10  شماره 

صفحات  -

تاریخ انتشار 2007